Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE, S71217, IEAT178 4A
MSDS Date:12/12/1997
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLPNR

Emergency Phone: 201-796-7100

Info Phone: 201-796-7100

Cage: DO274

Telephone: 201-796-7100

Cage: DO274

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE. (EINECS# 200-936-1)

CAS: 76-13-1

RTECS: KJ4000000

OSHA PEL 1000 PPM, 7600 MG/M3

ACGIH TLV: 1000 PPM, 7670 MG/M3

LD50 LC50 Mixture:ORAL, RAT: LD50 = 43 GM/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: CAUTION: MAY CAUSE
EYE IRRITATION. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING. MAY
CAUSE CENTRAL NERVOUS SYSTEM EFFECTS, RESPIRATORY AND DIGESTIVE
TRACT IRRITATION, CARDIAC DISTU RBANCES, DERMATITIS. TARGET ORGANS:
HEART, CENTRAL NERVOUS SYSTEM. POTENTIAL HEALTH EFFECTS: EYE:
CONTACT PRODUCES IRRITATION, TEARING, BURNING PAIN; MAY CAUSE
CONJUNCTIVITIS. SKIN: MAY CAUSE IRRITAT ION. PROLONGED/REPEATED
CONTACT MAY CAUSE DEFATTING OF SKIN AND DERMATITIS. INGESTION:
LARGE AMOUNTS MAY CAUSE GASTROINTESTINAL IRRITATION. EXPECTED TO BE
A LOW INGESTION HAZARD. INHALATION: INHALATIO N OF (SIGNS &
SYMPTOMS OF OVEREXPOSURE)
Explanation of
Carcinogenicity:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE-ACGIH: A4-NOT
CLASSIFIABLE AS A HUMAN CARCINOGEN.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT): HIGH
CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS
CHARACTERIZED BY HEADACHE, DIZZINESS, UNCONSCIOUSNESS AND COMA.
VAPOR REDUCES OXYGEN AVAILABLE FO R BREATHING. MAY CAUSE REPIRATORY
TRACT IRRITATION, HEART DISTURBANCES-POSSIBLY LEADING TO CARDIAC
ARREST AND DEATH. MAY CAUSE NARCOTIC EFFECTS IN HIGH CONCENTRATION.
CHLOROFLUOROCARBON (CFC) MATERIAL S MAY SENSITIZE THE HEART TO
EPINEPHRINE. THE USE OF EPINEPHRINE MAY BE CONTRA-INDICATED EXCEPT
FOR LIFE-SUSTAINING USES IN HUMANS EXPOSED TO CFC'S. CHRONIC:
PROLONGED OR REPEATED SKIN CONTACT MAY CA USE DEFATTING AND
DERMATITIS.

First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES,
OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. GET MEDICAL AID.
SKIN: FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES,
WHILE REMO VING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL AID IF
IRRITATION DEVELOPS OR PERSISTS. WASH CLOTHING BEFORE REUSE.
INGESTION: IF THE VICTIM IS CONSCIOUS AND ALERT, GIVE 2 - 4 CUPFULS
OF MILK OR WAT ER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL AID. INHALATION: REMOVE FROM EXPOSURE TO FRESH
AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING DIFFI CULT, GIVE OXYGEN. (OTHER INFORMATION)

Flash Point:NONE
Autoignition Temp:=680.C, 1256.F
Extinguishing Media:FOR SMALL FIRES, USDE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM. USE EXTINGUISHING MEDIA MOST
APPROPRIATE FOR THE SURROUNDING FIRE. (UNUSUAL FIRE & EXPLOSION
HAZARD)
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR
EQUIVALENT), AND FULL PROTECTIVE GEAR. DURING A FIRE, IRRITATING
AND HIGHLY TOXIC GASSES MAY BE GENERAT ED BY THERMAL DECOMPOSITION
OR COMBUSTION. VAPORS MAY BE FLAMMABLE IN VESSELS OF (UNUSUAL FIRE
AND EXPLOSION HAZARD)
Unusual Fire/Explosion Hazard:N/P. EXTINGUISHING MEDIA (CONT):
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER
FIRE IS OUT. FIRE FIGHTING PROCEDURE (CONT): ADEQUATE SIZE.
VAPORS MAY BE HEAVIER THAN AIR. THEY CAN SPREAD ALONG THE GROUND
AND COLLECT IN LOW OR CONFINED AREAS. NFPA RATING: NOT
PUBLISHED.

Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN (CONTROL MEASURES) SECTION.
SPILLS / LEAKS: ABSORB WITH INERT MATERIAL (E.G., DRY SAND OR
EARTH), THEN PLACE INTO A C HEMICAL WASTE CONTAINER. REMOVE ALL
SOURCES OF IGNITION. PROVIDE VENTILATION.

Handling and Storage Precautions:HANDLING: WASH THOROUGHLY AFTER
HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. USE
WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN AND EYES. AVOID
INGESTION AND INHALATION. STORAGE: KEEP FROM CONTACT WITH
OXIDIZING MATERIALS. STORE IN A COOL, DRY, (OTHER PRECAUTIONS)
Other Precautions:HANDLING AND STORAGE PRECAUTIONS (CONT):
WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY
FROM METALS. KEEP CONTAINERS TIGHTLY CLOSED. DO NOT STORE IN
ALUMINUM CONTAINERS.

Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN149 APPROVED RESPIRATOR WHEN NECESSARY.
EXPOSURE LIMITS (CONT INUED FROM INGREDIENT SECTION): NIOSH: 1000
PPM TWA, 7600 MG/M3 TWA.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL
AIRBORNE LEVELS. USE PROCESS ENCLOSURE, LOCAL EXHAUST VENTILATION
OR (SUPPLEMENTAL SAFETY AND HEALTH)
Protective Gloves:WEAR APPROPRIATE (IMPERVIOUS - ) PROTECTIVE GLOVES TO
PREVENT SKIN EXPOSURE
Eye Protection:WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR (SUPPLEMENTAL
SAFETY AND HEALTH)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . CLOTHING: WEAR APPROPRIATE PROTECTIVE CLOTHING
TO MINIMIZE CONTACT WITH SKIN.
Work Hygienic Practices:N/P. NO SMOKING IN AREA OF USE. DO NOT USE
IN THE VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT
AND / OR UV RADIATION MAY CAUSE THE FORMATION OF FLUORIDES,
CHLORIDES AND PHOSGENE
Supplemental Safety and Health
VENTILATION (CONT): OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. EYE PROTECTION
(CONT): CHEMICAL SAFETY GOGGLES AS DESCRIBED BY OSHA'S EYE AND FACE
P ROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD
EN166

Boiling Pt:=45.8C, 114.4F
Melt/Freeze Pt:=-36.4C, -33.5F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:273 MMHG @ 20C
Vapor Density:6 (AIR=1)
Spec Gravity:1.6 @ 25C
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:0.45 (ACETONE=1)
Solubility in Water:0.028%
Appearance and Odor:CLEAR, COLORLESS LIQUID; ETHEREAL ODOR (WEAK ODOR).

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS SUCH AS SODIUM, POTASSIUM, ALUMINUM,
BARIUM, LITHIUM, SAMARIUM, SODIUM-POTASSIUM ALLOY, TITANIUM, ZINC,
MAGNESIUM AND BERYLLIUM.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID INCOMPATIBLE MATERIALS, IGNITION SOURCES, METALS,
STRONG OXIDANTS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CARBON
MONOXIDE, IRRITATING AND TOXIC FUMES AND GASES, CARBON DIOXIDE,
HYDROGEN FLUORIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA P-SERIES: NONE LISTED. RCRA
U-SERIES: NONE LISTED.

Toxicological Information:EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE
EFFECTS, NEUROTOXICITY, MUTAGENICITY: NO INFORMATION AVAILABLE.
OTHER STUDIES: NO DATA AVAILABLE. FEDERAL REGULATORY
(CONT): OF THE CHEMICALS IN THI S PRODUCT ARE LISTED AS HAZARDOUS
SUBSTANCES UNDER THE CWA. NONE OF THE CHEMICALS IN PRODUCT ARE
LISTED AS PRIORITY POLLUTANTS UNDER THE CWA. NONE OF THE CHEMICALS
IN THIS PRODUCT ARE LISTED AS TOX IC POLLUTANTS UNDER THE CWA.
OSHA: NONE OF THE CHEMICALS IN THIS PRODUCT ARE CONSIDERED HIGHLY
HAZARDOUS BY OSHA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: HAS VERY
LIMITED SOLUBILITY IN WATER AND IS HIGHLY VOLATILE. EXPECTED TO BE
EVENTUALLY CONVEYED TO ATMOSPHERE. HAS SOME POTENTIAL TO PETURB
STRATOSPHER IC OZONE. PHYSICAL / CHEMICAL: NOT AVAILABLE. OTHER:
NOT AVAILABLE. STATE REGULATORY (CONT): WGK (WATER DANGER /
PROTECTION) CAS # 76-13-1: 2. CANADA: CAS # 76-13-1 IS LISTED ON
CANADA'S DS L / NDSL LIST. THIS PRODUCT HAS A WHMIS CLASSIFICATION
OF D2B. CAS # 76-13-1 IS NOT LISTED ON CANADA'S INGREDIENT
DISCLOSURE LIST. EXPOSURE LIMITS CAS 76-13-1: OEL - AUSTRALIA:
TWA 1000 PPM (7600 MG/M3); STEL 1250 PPM. (TRANSPORT INFO)

Transport Information:US DOT: NO INFORMATION AVAILABLE. CANADIAN TDG:
NO INFORMATION AVAILABLE. ECOLOGICAL INFO (CONT): OEL -
BELGIUM: TWA 1000 PPM (7670 MG/M3); STEL 1250 PPM. OEL - DENMARK:
TWA 500 PPM (3800 MG/ M3). OEL - FINLAND: TWA 1000 PPM (7600
MG/M3); STEL 1250 PPM. OEL - FRANCE: TWA 1000 PPM (7600 MG/M3);
STEL 1250 PPM. OEL - GERMANY: TWA 500 PPM (3800 MG/M3). OEL -
HUNGARY: STEL 40 MG/M3. OEL - JAPAN: TWA 500 PPM (380 MG/M3).
OEL - THE NETHERLANDS: TWA 1000 PPM (7600 MG/M3). OEL - THE
PHILLIPINES: TWA 1000 PPM (7600 MG/M3). OEL - RUSSIA: TWA 500 PPM;
STEL 5000 MG/M3. OEL - SWEEDEN: TWA 5 00 PPM (4000 MG/M3); (SARA
III)

SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS# 76-13-1: ACUTE,
CHRONIC. SECTION 313: THIS MATERIAL CONTAINS 1,1,2-
TRICHLORO-1,2,2-TRIFLUOR (CAS# 76-13-1, 100%), WHICH IS SUBJECT TO
REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40 CFR
PART 372. TRANSPORT INFO (CONT): STEL 750 PPM (6000 MG/M3).
OEL - SWITZERLAND: TWA 500 PPM (3800 MG/M3). OEL - TURKEY: TWA
1000 PPM (7600 MG/M3). OEL - UNITED KINGDOM: TWA 1000 PPM (7600
MG/M3); STEL 1250 PPM. OEL IN BULGARIA, CO LOMBIA CHECK ACGIH TLV.
(OTHER INFO)
Federal Regulatory Information:TSCA CAS# 76-13-1 IS LISTED ON TSCA
INVENTORY. HEALTH AND SAFETY REPORTING LIST CAS# 76-13-1:
EFFECTIVE DATE 13 APRIL 1989; SUNSET DATE 19 DEC 1995. CHEMICAL
TEST RULES: NONE OF CHEMICALS IN THIS PR ODUCT ARE UNDER CHEMICAL
TEST RULE. SECTION 12B: NONE OF CHEMICALS LISTED UNDER TSCA
SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMICALS IN
THIS MATERIAL HAVE A SNUR UNDER TSCA. CLEAN AI R ACT: THIS
MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS. DEPLETION
POTENTIAL = 0.8; GLOBA L WARMING POTENTIAL = 5000 (20). THIS
MATERIAL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER
ACT: NONE OF (TOXICOLOGICAL INFO)
State Regulatory Information:1,1,2-TRICHLORO-1,2,2-TRIFLUOR CAN BE
FOUND ON THE FOLLOWING STATE RIGHT-TO-KNOW LISTS: CALIFORNIA, NEW
JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS.
CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN
THIS PRODUCT ARE LISTED. EUROPEAN / INTERNATIONAL REGULATIONS:
EUROPEAN LABELING IN ACCORDANCE WITH EC DIRECTIVES: HAZARD SYMBOLS:
XN N. RISK PHRASES: R 20/22 HARMFUL BY I NHALATION AND IF
SWALLOWED, R 59 DANGEROUS FOR OZONE LAYER. SAFETY PHRASES: S 44 IF
YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE
POSSIBLE); S 9 KEEP THE CONTAINER IN A WELL-VENTILATED PLACE.
(ECOLOGICAL INFO)